| Sr.No. | Name | To | From |
|---|---|---|---|
| 1 | Mr. Dindayal Gupta | 09-12-1959 | 11-02-1965 |
| 2 | Mr. V. S. Page | 12-02-1965 | 15-03-1979 |
| 3 | Mr. Shirubhau Limaye | 16-03-1979 | 14-10-1980 |
| 4 | Mr. P. K. Sawant | 15-10-1980 | 14-10-1983 |
| 5 | Mr. Tryambak Shivram Bharde | 15-03-1984 | 14-03-1987 |
| 6 | Dr. Jayantrao Patil | 14-04-1987 | 21-08-1991 |
| 7 | Mr. Prabhakar Kunte | 19-09-1991 | 17-05-1995 |
| 8 | Dr. Shantrambapu Karmalkar | 07-09-1995 | 06-09-1999 |
| 9 | MLA Dr. Vijaykumar Gavit | 16-06-2000 | 13-06-2001 |
| 10 | MLA Mr. V. M. Patel | 13-06-2001 | 31-12-2004 |
| 11 | Prof. Lakshman Dhobale | 02-09-2006 | 14-06-2012 |
| 12 | Mr. Suresh Aadgonda Patil | 19-07-2013 | 06-12-2014 |
| 13 | Mr. Vishal Chordia | 16-09-2016 | |
| 14 | Mr. Ravindra Sathe | 01-12-2022 |
| Sr. No. | Name | To | From |
|---|---|---|---|
| 1 | V. K. Kalghatagi | 20-01-1961 | 31-03-1969 |
| 2 | P. M. Kavade | 01-04-1971 | 30-06-1972 |
| 3 | P. S. Nadkarni IAS | 01-07-1972 | 26-02-1975 |
| 4 | K. V. Nashikkar IAS | 27-02-1975 | 29-05-1977 |
| 5 | P. P. Dev IAS | 01-01-1978 | 05-12-1979 |
| 6 | B. M. Parkar IAS | 02-05-1980 | 31-12-1988 |
| 7 | R. Y. Gaikwad IAS | 01-01-1989 | 02-09-1990 |
| 8 | Ashok Sinha IAS | 10-09-1990 | 16-08-1992 |
| 9 | Dr. Munshilal Gautam IAS | 17-08-1992 | 30-04-1993 |
| 10 | B. B. Patil IAS | 01-05-1993 | 24-05-1991 |
| 11 | R. S. Negi IAS | 25-05-1995 | 06-08-1997 |
| 12 | A.R. Dalwai IAS | 01-12-1997 | 12-12-1997 |
| 13 | A.M Reddy IAS | 13-12-1997 | 24-04-1998 |
| 14 | Kumud Bansal IAS | 04-05-1998 | 31-08-1998 |
| 15 | D.B.S.Sohal IAS | 01-09-1998 | 02-03-1999 |
| 16 | Rani A. Jadhav IAS | 03-03-1999 | 28-05-2000 |
| 17 | Ana Dani IAS | 04-06-2000 | 11-08-2000 |
| 18 | Mitali Sen-Gawai IAS | 12-08-2000 | 07-09-2001 |
| 19 | Dr. Rameshchandra Sagar IAS | 17-10-2001 | 29-01-2004 |
| 20 | M. Ramswami IAS | 05-05-2004 | 04-09-2006 |
| 21 | Sanjay Sawant IAS | 04-09-2006 | 19-04-2007 |
| 22 | Preetam Athavale | 22-01-2007 | 28-05-2007 |
| 23 | Shirish Karle IAS | 20-04-2007 | 27-05-2008 |
| 24 | Dr. Harshdeep Kamble IAS | 29-05-2008 | 05-02-2009 |
| 25 | Tanaji Satre IAS | 05-03-2009 | 25-03-2010 |
| 26 | Tukaram Mundhe IAS | 28-05-2010 | 20-06-2011 |
| 27 | Subhash Sonavane IAS | 01-08-2011 | 31-10-2012 |
| 28 | Ramesh Devkar IAS | 28-01-2013 | 04-05-2016 |
| 29 | Richa Bagla IAS | 04-05-2016 | 09-03-2018 |
| 30 | Dr. M. N. Kerketta IAS | 04-05-2018 | 02-07-2021 |
| 31 | Anshu Sinha IAS | 02-07-2021 | 06-06-2023 |
| 32 | Rajendra Nimbalkar | 07-06-2023 | 10-07-2023 |
| 33 | Smt. R Vimala | 10-07-2023 | – |